Alkene Polymerization Reactions with Transition Metal Catalysts

Written By Yury Kissin
Alkene Polymerization Reactions with Transition Metal Catalysts
  • Publsiher : Elsevier
  • Release : 10 March 2008
  • ISBN : 9780080557991
  • Pages : 495 pages
  • Rating : 4/5 from 21 reviews
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Read or download book entitled Alkene Polymerization Reactions with Transition Metal Catalysts written by Yury Kissin which was release on 10 March 2008, this book published by Elsevier. Available in PDF, EPUB and Kindle Format. Book excerpt: During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
  • Author : Yury Kissin
  • Publisher : Elsevier
  • Release Date : 2008-03-10
  • Total pages : 495
  • ISBN : 9780080557991
GET BOOK

Summary : During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and ...

Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
  • Author : Y. V. Kissin
  • Publisher : Elsevier Science & Technology
  • Release Date : 2008
  • Total pages : 592
  • ISBN : 9780080557991
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Summary : During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and ...

Alkene Polymerization Reactions with Transition Metal Catalysts Studies in Surface Science and Catalysis

Alkene Polymerization Reactions with Transition Metal Catalysts  Studies in Surface Science and Catalysis
  • Author : Kissin YV.
  • Publisher : Unknown
  • Release Date : 2008
  • Total pages : 212
  • ISBN : 9780080557991
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Summary : Download or read online Alkene Polymerization Reactions with Transition Metal Catalysts Studies in Surface Science and Catalysis written by Kissin YV., published by which was released on 2008. Get Alkene Polymerization Reactions with Transition Metal Catalysts Studies in Surface Science and Catalysis Books now! Available in PDF, ePub and Kindle....

Handbook of Transition Metal Polymerization Catalysts

Handbook of Transition Metal Polymerization Catalysts
  • Author : Ray Hoff
  • Publisher : John Wiley & Sons
  • Release Date : 2018-04-20
  • Total pages : 768
  • ISBN : 9780080557991
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Summary : Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new ...

Introduction to Industrial Polypropylene

Introduction to Industrial Polypropylene
  • Author : Dennis B. Malpass,Elliot Band
  • Publisher : John Wiley & Sons
  • Release Date : 2012-07-02
  • Total pages : 360
  • ISBN : 9780080557991
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Summary : This introductory text is an important resource for new engineers, chemists, students, and chemical industry personnel to understand the technical aspects of polypropylene which is the 2nd largest synthetics polymer in manufactured output. The book considers the following topics: What are the principal types of polypropylene and how do they ...

Inorganic Reactions and Methods The Formation of Bonds to Transition and Inner Transition Metals

Inorganic Reactions and Methods  The Formation of Bonds to Transition and Inner Transition Metals
  • Author : A. P. Hagen
  • Publisher : John Wiley & Sons
  • Release Date : 2009-09-17
  • Total pages : 724
  • ISBN : 9780080557991
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Summary : Boasting numerous industrial applications, inorganic chemistry forms the basis for research into new materials and bioinorganic compounds such as calcium that act as biological catalysts. Now complete, this highly acclaimed series presents current knowledge in all areas of inorganic chemistry, including chemistry of the elements; organometallic, polymeric and solid-state materials; ...

Homogeneous Transition metal Catalysis

Homogeneous Transition metal Catalysis
  • Author : Christopher Masters
  • Publisher : Springer Science & Business Media
  • Release Date : 2012-12-06
  • Total pages : 278
  • ISBN : 9780080557991
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Summary : Soluble catalysts are used extensively in many branches of chemistry and are indeed a vital constituent of many natural processes. They find wide application throughout the chemical industry where they assist in the production of several million tonnes of chemicals each year. Since homogeneous systems, especially those incorporating transition metals, ...

Activation Of Alkenes And Alkynes

Activation Of Alkenes And Alkynes
  • Author : M.M. Taqui Khan
  • Publisher : Elsevier
  • Release Date : 2012-12-02
  • Total pages : 208
  • ISBN : 9780080557991
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Summary : Homogeneous Catalysis by Metal Complexes, Volume II: Activation of Alkenes and Alkynes reviews and systematizes the chemistry of metal ion activation of alkenes and alkynes. The book presents the migration of ? bonds; the oxo reaction; and the hydrosilation of alkenes and alkynes. The text also covers topics on the oxidation ...

Handbook of Industrial Polyethylene and Technology

Handbook of Industrial Polyethylene and Technology
  • Author : Mark A. Spalding,Ananda Chatterjee
  • Publisher : John Wiley & Sons
  • Release Date : 2017-10-12
  • Total pages : 1410
  • ISBN : 9780080557991
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Summary : This handbook provides an exhaustive description of polyethylene. The 50+ chapters are written by some of the most experienced and prominent authors in the field, providing a truly unique view of polyethylene. The book starts with a historical discussion on how low density polyethylene was discovered and how it provided unique ...

Carraher s Polymer Chemistry Tenth Edition

Carraher s Polymer Chemistry  Tenth Edition
  • Author : Charles E. Carraher Jr.
  • Publisher : CRC Press
  • Release Date : 2017-10-12
  • Total pages : 794
  • ISBN : 9780080557991
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Summary : Carraher's Polymer Chemistry, Tenth Edition integrates the core areas of polymer science. Along with updating of each chapter, newly added content reflects the growing applications in Biochemistry, Biomaterials, and Sustainable Industries. Providing a user-friendly approach to the world of polymeric materials, the book allows students to integrate their chemical knowledge ...

Introduction to Polymer Chemistry

Introduction to Polymer Chemistry
  • Author : Charles E. Carraher Jr.
  • Publisher : CRC Press
  • Release Date : 2017-01-06
  • Total pages : 560
  • ISBN : 9780080557991
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Summary : Introduction to Polymer Chemistry provides undergraduate students with a much-needed, well-rounded presentation of the principles and applications of natural, synthetic, inorganic, and organic polymers. With an emphasis on the environment and green chemistry and materials, this fourth edition continues to provide detailed coverage of natural and synthetic giant molecules, inorganic ...

Introduction to Polymer Chemistry Third Edition

Introduction to Polymer Chemistry  Third Edition
  • Author : Charles E. Carraher Jr.
  • Publisher : CRC Press
  • Release Date : 2012-12-04
  • Total pages : 554
  • ISBN : 9780080557991
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Summary : Continuing the tradition of its previous editions, the third edition of Introduction to Polymer Chemistry provides a well-rounded presentation of the principles and applications of natural, synthetic, inorganic, and organic polymers. With an emphasis on the environment and green chemistry and materials, this third edition offers detailed coverage of natural ...

Carraher s Polymer Chemistry Ninth Edition

Carraher s Polymer Chemistry  Ninth Edition
  • Author : Charles E. Carraher Jr.
  • Publisher : CRC Press
  • Release Date : 2013-09-05
  • Total pages : 818
  • ISBN : 9780080557991
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Summary : Most of the advancements in communication, computers, medicine, and air and water purity are linked to macromolecules and a fundamental understanding of the principles that govern their behavior. These fundamentals are explored in Carraher's Polymer Chemistry, Ninth Edition. Continuing the tradition of previous volumes, the latest edition provides a well-rounded ...

Carraher s Polymer Chemistry Eighth Edition

Carraher s Polymer Chemistry  Eighth Edition
  • Author : Charles E. Carraher Jr.
  • Publisher : CRC Press
  • Release Date : 2010-10-13
  • Total pages : 824
  • ISBN : 9780080557991
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Summary : Updated to reflect a growing focus on green chemistry in the scientific community and in compliance with the American Chemical Society’s Committee on Professional Training guidelines, Carraher’s Polymer Chemistry, Eighth Edition integrates the core areas that contribute to the growth of polymer science. It supplies the basic understanding ...

Catalysis

Catalysis
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  • Publisher : John Wiley & Sons
  • Release Date : 2018-02-20
  • Total pages : 384
  • ISBN : 9780080557991
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Summary : Written by an excellent, highly experienced and motivated team of lecturers, this textbook is based on one of the most successful courses in catalysis and as such is tried-and-tested by generations of graduate and PhD students, i.e. the Catalysis-An-Integrated-Approach (CAIA) course organized by NIOK, the Dutch Catalysis research school. ...